By Jeffrey M. Lemm
The examine of the constitution of molecular platforms is a permanent region of analysis. This sequence is dedicated to bringing jointly articles from best staff within the box that draw jointly contemporary theoretical and experimental effects and advances in figuring out.
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Extra resources for Advances in Molecular Structure Research
The fundamental packing motif in both crystal forms of Ru6C(CO)I 7 is characterized by rows of molecules linked via a "key-keyhole" interaction of the kind discussed above for Ru3(CO)I 2 (see Figure 11). -I 3 0 0 m. -,I --,I r- 0 O ~ l -% 9 % b (continued) Figure 10. Solid state molecular structures of the three conformers of Ru6C(CO)17 (a), (b), and (r note how the three molecules differ chiefly in the rotameric conformation of the tricarbonyl units above and below the octahedron equatorial plane containing the bridging CO ligands.
J. Am. Chem. Soc. 1975, 97, 764. (b) Hoye, T. ; Peck, D. " Swanson, T. A. J. Am. Chem. Soc. 1984, 106, 2738. 25. The notation[C;] or ~-qmeans a gauche sequence containing the large absolute dihedral angle near 100~ 26. Some of the 6-31G*-optimized values given in Scheme 2 are taken from Wiberg, K. " Murcko, M. A. J. Am. Chem. Soc. 1988, 110, 8029. 27. ; Yamato, M. Tetrahedron 1993, 49, 387. 28. I had noticed this phenomenon soon after I started using molecular mechanics in the mid-1970s [Osawa, E.
ABSTRACT The structures of representative examples of transition metal cluster complexes are discussed in terms of the interplay between intramolecular and intermolecular interactions. ) and crystal properties Advances in Molecular Structure Research Volume 2, pages 25-65 Copyright 9 1996 by JAI Press Inc. All rights of reproduction in any form reserved. ISBN: 1-7623-0025-6 25 25 26 27 28 39 51 57 61 62 62 26 DARIO BRAGA and FABRIZIA GREPIONI (intermolecular interlocking, cohesion, and solid state dynamics).
Advances in Molecular Structure Research by Jeffrey M. Lemm